819 research outputs found
Thermodynamic stabilities of ternary metal borides: An ab initio guide for synthesizing layered superconductors
Density functional theory calculations have been used to identify stable
layered Li--B crystal structure phases derived from a recently proposed
binary metal-sandwich (MS) lithium monoboride superconductor. We show that the
MS lithium monoboride gains in stability when alloyed with electron-rich metal
diborides; the resulting ordered LiB ternary phases may form
under normal synthesis conditions in a wide concentration range of for a
number of group-III-V metals . In an effort to pre-select compounds with the
strongest electron-phonon coupling we examine the softening of the in-plane
boron phonon mode at in a large class of metal borides. Our results
reveal interesting general trends for the frequency of the in-plane boron
phonon modes as a function of the boron-boron bond length and the valence of
the metal. One of the candidates with a promise to be an MgB-type
superconductor, LiAlB, has been examined in more detail: according to
our {\it ab initio} calculations of the phonon dispersion and the
electron-phonon coupling , the compound should have a critical
temperature of K.Comment: 10 pages, 9 figures, submitted to PR
Theoretical study of metal borides stability
We have recently identified metal-sandwich (MS) crystal structures and shown
with ab initio calculations that the MS lithium monoboride phases are favored
over the known stoichiometric ones under hydrostatic pressure [Phys. Rev. B 73,
180501(R) (2006)]. According to previous studies synthesized lithium monoboride
tends to be boron-deficient, however the mechanism leading to this phenomenon
is not fully understood. We propose a simple model that explains the
experimentally observed off-stoichiometry and show that compared to such
boron-deficient phases the MS-LiB compounds still have lower formation enthalpy
under high pressures. We also investigate stability of MS phases for a large
class of metal borides. Our ab initio results suggest that MS noble metal
borides are less unstable than the corresponding AlB-type phases but not
stable enough to form under equilibrium conditions.Comment: 14 pages, 15 figure
Symbolic approach and induction in the Heisenberg group
We associate a homomorphism in the Heisenberg group to each hyperbolic
unimodular automorphism of the free group on two generators. We show that the
first return-time of some flows in "good" sections, are conjugate to
niltranslations, which have the property of being self-induced.Comment: 18 page
Spectra of Discrete Schr\"odinger Operators with Primitive Invertible Substitution Potentials
We study the spectral properties of discrete Schr\"odinger operators with
potentials given by primitive invertible substitution sequences (or by Sturmian
sequences whose rotation angle has an eventually periodic continued fraction
expansion, a strictly larger class than primitive invertible substitution
sequences). It is known that operators from this family have spectra which are
Cantor sets of zero Lebesgue measure. We show that the Hausdorff dimension of
this set tends to as coupling constant tends to . Moreover, we
also show that at small coupling constant, all gaps allowed by the gap labeling
theorem are open and furthermore open linearly with respect to .
Additionally, we show that, in the small coupling regime, the density of states
measure for an operator in this family is exact dimensional. The dimension of
the density of states measure is strictly smaller than the Hausdorff dimension
of the spectrum and tends to as tends to
Geometric representation of interval exchange maps over algebraic number fields
We consider the restriction of interval exchange transformations to algebraic
number fields, which leads to maps on lattices. We characterize
renormalizability arithmetically, and study its relationships with a
geometrical quantity that we call the drift vector. We exhibit some examples of
renormalizable interval exchange maps with zero and non-zero drift vector, and
carry out some investigations of their properties. In particular, we look for
evidence of the finite decomposition property: each lattice is the union of
finitely many orbits.Comment: 34 pages, 8 postscript figure
Super-Earths: A New Class of Planetary Bodies
Super-Earths, a class of planetary bodies with masses ranging from a few
Earth-masses to slightly smaller than Uranus, have recently found a special
place in the exoplanetary science. Being slightly larger than a typical
terrestrial planet, super-Earths may have physical and dynamical
characteristics similar to those of Earth whereas unlike terrestrial planets,
they are relatively easier to detect. Because of their sizes, super-Earths can
maintain moderate atmospheres and possibly dynamic interiors with plate
tectonics. They also seem to be more common around low-mass stars where the
habitable zone is in closer distances. This article presents a review of the
current state of research on super-Earths, and discusses the models of the
formation, dynamical evolution, and possible habitability of these objects.
Given the recent advances in detection techniques, the detectability of
super-Earths is also discussed, and a review of the prospects of their
detection in the habitable zones of low-mass stars is presented.Comment: A (non-technical) review of the literature on the current state
ofresearch on super-Earths. The topics include observation, formation,
dynamical evolution, habitability, composition, interior dynamics, magnetic
field, atmosphere, and propsect of detection. The article has 44 pages, 27
figures, and 203 references. It has been accepted for publication in the
journal Contemporary Physics (2011
Temperature-controlled laminar airflow in severe asthma for exacerbation reduction (The LASER Trial): study protocol for a randomised controlled trial
BackgroundAsthma affects more than 5 million patients in the United Kingdom. Nearly 500,000 of these patients have severe asthma with severe symptoms and frequent exacerbations that are inadequately controlled with available treatments. The burden of severe asthma on the NHS is enormous, accounting for 80 % of the total asthma cost (ÂŁ1 billion), with frequent exacerbations and expensive medications generating much of this cost.Of those patients with severe asthma, 70 % are sensitised to indoor aeroallergens, and the level of exposure to allergens determines the symptoms; patients exposed to high levels are therefore most at risk of exacerbations and hospital admissions.The LASER trial aims to assess whether a new treatment, temperature controlled laminar airflow (TLA) delivered by the Airsonettâą device, can reduce the frequency of exacerbations in patients with severe allergic asthma by reducing exposure to aeroallergens overnight.MethodsThis multicentre study is a placebo-controlled, blinded, randomised controlled, parallel group trial. A total of 222 patients with a new or current diagnosis of severe allergic asthma will be assigned with a random element in a 1:1 ratio to receive either an active device for one year or a placebo device. The primary outcome is the frequency of severe asthma exacerbations occurring over a 12-month period, defined in accordance with the American Thoracic Society/European Respiratory Society (ATS/ERS) guidelines. Secondary outcomes include changes in asthma control, lung function, asthma-specific and global quality of life for participants and their carers, adherence to intervention, healthcare resource use and costs, and cost-effectiveness. Qualitative interviews will be conducted to elicit participantâs and their partnerâs perceptions of the treatment.DiscussionEffective measures of allergen avoidance have, to date, proved elusive. The LASER trial aims to address this. The study will ascertain whether home-based nocturnal TLA usage over a 12-month period can reduce the frequency of exacerbations and improve asthma control and quality of life as compared to placebo, whilst being cost-effective and acceptable to adults with poorly controlled, severe allergic asthma. The results of this study will be widely applicable to the many patients with allergic asthma both in the UK and internationally.Trial registrationCurrent controlled trials ISRCTN46346208 (Date assigned 22 January 2014)
The complexity of tangent words
In a previous paper, we described the set of words that appear in the coding
of smooth (resp. analytic) curves at arbitrary small scale. The aim of this
paper is to compute the complexity of those languages.Comment: In Proceedings WORDS 2011, arXiv:1108.341
The solvation and dissociation of 4-benzylaniline hydrochloride in chlorobenzene
A reaction scheme is proposed to account for the liberation of 4-benzylaniline from 4-benzylaniline hydrochloride, using chlorobenzene as a solvent at a temperature of 373 K. Two operational regimes are explored: âclosedâ reaction conditions correspond to the retention of evolved hydrogen chloride gas within the reaction medium, whereas an âopenâ system permits gaseous hydrogen chloride to be released from the reaction medium. The solution phase chemistry is analyzed by 1H NMR spectroscopy. Complete liberation of solvated 4-benzylaniline from solid 4-benzylaniline hydrochloride is possible under âopenâ conditions, with the entropically favored conversion of solvated hydrogen chloride to the gaseous phase thought to be the thermodynamic driver that effectively controls a series of interconnecting equilibria. A kinetic model is proposed to account for the observations of the open system
An Evaluation of Agreement of Breathing Rates Measured by a Novel Device, Manual Counting, and Other Techniques Used in Clinical Practice: Protocol for the Observational VENTILATE Study.
BACKGROUND: Respiratory rate (RR) is the most sensitive physiological observation to predict clinical deterioration on hospital wards, and poor clinical monitoring has been highlighted as a primary contributor to avoidable mortality. Patients in intensive care have their RR monitored continuously, but this equipment is rarely available on general hospital wards. OBJECTIVE: The primary objective is to assess the accuracy of the RespiraSense device in comparison with other methods currently used in clinical practice. The secondary objective is to assess the accuracy of the RespiraSense device in participants in different positions and when reading aloud. METHODS: A single-center, prospective observational study will investigate the agreement of the RespiraSense device as compared with other device measurements (capnography, electrocardiogram) and the current standard measurement of RR (manual counting by a trained health care professional). The different methods will be employed concurrently on the same participant as part of a single study visit. RESULTS: Recruitment to this study has not yet started as funding decisions are still pending. Therefore, results are not available at this stage. It is anticipated that the data required could be collected within 2 months of first recruitment to the study and data analysis completed within 6 months of the study start date. CONCLUSIONS: The Evaluation of Agreement of Breathing Rates Measured by a Novel Device, Manual Counting, and Other Techniques Used in Clinical Practice (VENTILATE) study will provide further validation of the use of the RespiraSense device in subjects with abnormal respiratory rates. INTERNATIONAL REGISTERED REPORT IDENTIFIER (IRRID): PRR1-10.2196/15437
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